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11.
Optically stimulated luminescence (OSL) dating was applied to quartz samples recovered from the gravel sediments of deformed marine terrace at the Suryum site, southeastern Korea, but has yielded stratigraphically inconsistent ages. Micromorphological, chemical, and mineralogical analyses of the gravels indicate the possible influence of chemical weathering on the apparent OSL ages. In the course of weathering after emerging from beach environments, originally permeable gravels underwent infilling by halloysite-rich clays in their voids, export and import of radioactive elements, and loss of mechanical strength with the creation of a porosity within pebbles. Calculation based on the evolution of the weathering profile showed a severe fluctuation of dose rate caused by the change of water content and radioactive element concentrations. Samples recovered from the weathering profile inevitably include quartz grains derived from mechanically weakened pebbles or illuviated from the upper layer, making it difficult to determine the equivalent dose (De) values of exclusively depositional quartz sands. Quantitative evaluation of the change of fabric and chemistry of the sediments on the basis of pedologic insight significantly aids in the derivation of OSL ages consistent with geomorphology and other independent age controls. 相似文献
12.
The crustal-scale Kyonggi shear zone of central Korea has been identified as a major boundary between the Precambrian Kyonggi massif in the south and the Imjingang belt in the north. The latter is an eastward extension of the Qinling-Dabie-Sulu collisional belt of China. Field observations and microstructural analysis indicate that the extensional shear zone evolved from a deep crustal ductile regime to a shallow crustal brittle regime, associated with a rapid uplift of the Kyonggi massif following the Late Permian-Early Triassic collision between the Sino-Korean and Yangtze cratons. A Rb-Sr muscovite age (226+/-1.2 Ma) of the mylonite suggests that the extensional ductile shearing occurred during the Late Triassic. 相似文献
13.
14.
A three-dimensional multi-level turbulence model is developed to simulate tide induced circulation in coastal waters. Based on the bathymetry data, the coastal waters are divided into a number of layers. In every layer, the velocities are integrated along the layer depth. The eddy viscosity and diffusivity are computed from the Prandtl mixing length turbulence model. This multi-level model solves for the water surface elevations and currents in different water depths. Comparison of numerical results with the measured data shows good conformity. 相似文献
15.
Sung-Chul Kim Jae E. Yang Dong-Kuk Kim Young-Wook Cheong Jeffrey Skousen Yeong-Sang Jung 《Environmental Earth Sciences》2012,66(1):327-335
Heavy metals in tailings and mining wastes from abandoned mines can be released into adjacent agricultural field and bioaccumulated
in crops or vegetables. Therefore, prediction of metal bioavailability has become an important issue to prevent adverse effect
of bioaccumulated metals on human health. In this study, single and sequential extraction methods were compared using multivariate
analysis to predict the bioavailability of Cd and As in contaminated rhizosphere soils. Single extraction using 0.1 M HCl
for Cd and 1.0 M HCl for As had an extraction efficiency of 8–12% for soil Cd and 14–17% for soil As compared to total concentration
extracted with aqua regia. Using sequential extraction, Fe–Mn-bound Cd (FR3) and residual Cd (FR5) were the dominant fractions
representing 43 and 41% of total Cd concentration. For As, the strongly absorbed form (FR2) was the most abundant chemical
fraction showing 45–54% of the total As concentration in soil. Multivariate analyses showed that single extraction with HCl
and total concentration of Cd and As in soil were significantly correlated to potato and green onion plant tissue metal concentration.
Although little information was obtained with multiple regression analysis because of multicollinearity of variables, the
result of principle component analysis (PCA) revealed that the highest positive loading was obtained using total concentration
of Cd and As in soil in the first principle component (PC1). In addition, total concentration of Cd and As in soil was independently
grouped with other chemical fractions by cluster analysis. Therefore, the overall result of this research indicated that total
concentrations of Cd and As in rhizosphere soils were the best predictors of bioavailability of heavy metals in these contaminated
soils. 相似文献
16.
Stabilization of arsenic-contaminated mine tailings using natural and calcined oyster shells 总被引:1,自引:0,他引:1
Deok Hyun Moon Kyoung-Woong Kim In-Ho Yoon Dennis G. Grubb Dae-Yewn Shin Kyung Hoon Cheong Hyung-Il Choi Yong Sik Ok Jeong-Hun Park 《Environmental Earth Sciences》2011,64(3):597-605
Natural oyster shells (NOS) and calcined oyster shells (COS) were used to immobilize arsenic (As) from contaminated mine tailings.
In addition, a blend of Portland cement (PC)/cement kiln dust (CKD) was used as a stabilizing agent. The Korean Standard Test
(KST) method (1 N HCl extraction) was used to evaluate the effectiveness of the treatment. The experimental results showed
that COS effectively immobilized As in treated mine tailings. Specifically, an As concentration less than 1 mg L−1 was obtained following COS treatment at 25 and 30 wt%. However, all the samples subjected to NOS treatments failed the Korean
warning standard of 1.2 mg L−1 after 28 days of curing. All of the COS-PC treatments were successful meeting the Korean warning standard after 7 days of
curing. However, the PC-only treatment failed to meet the Korean warning standard. Similarly, the CKD-only treatment was failed
to meet the Korean warning standard after 7 days of curing. However, the COS-CKD treatment showed that when the COS content
was greater than 20 wt%, less than 1 mg L−1 of As leachability was obtained. Scanning electron microscopy–energy dispersive X-ray spectroscopy (SEM–EDX) showed needle-like
and torpedo-like Ca–As phases in the COS-treated samples suggesting that As was strongly associated with Ca and O. X-ray absorption
near edge structure (XANES) analyses confirmed that As(V) was prevalent in the tailings and that there were no changes in
As speciation following NOS or COS treatment. 相似文献
17.
Spectral analysis method for a limited area using the eigenmodes of the spherical Laplacian operator
We propose a spectral analysis method using the eigenmodes of the spherical Laplacian operator on the limited area domain. Two numerical methods are considered for the horizontal discretization: One uses the half-ranged Fourier series for both longitudinal and latitudinal directions, and the other uses the Fourier finite-element method with piecewise linear basis functions for the latitudinal direction. The field variable for the two numerical algorithms is represented as linear combinations of the eigenvectors of the Laplacian operator on the limited area domain; we define the one-dimensional spectrum with the eigenvector coefficients as a function of the indices equivalent to the total wavenumbers of the Laplacian operator on the global domain. The spatial robustness of this method was verified through the self-consistency test comparing the spectra of isotropic Gaussian bells on the sphere. We used the method in the kinetic energy spectral analysis for a limited area with global atmospheric data, and compared the results for different seasons. The kinetic energy spectra represented the well-known characteristics with scale and different powers with season. 相似文献
18.
19.
T.V. Donskaya D.P. Gladkochub V.S. Fedorovsky A.M. Mazukabzov M. Cho W. Cheong J. Kim 《Russian Geology and Geophysics》2013,54(10):1205-1218
We present geological, structural, and geochemical data on synmetamorphic granitoids from the Tutai and South Ol’khon plutons of the Ol’khon terrane (Central Asian Fold Belt) with an estimation of the U–Pb zircon age of the Tutai granites. The structural and petrological data suggest the synfolding and synmetamorphic origin of the granitoids. The U–Pb zircon age of the Tutai granites (488.6 ± 8.0 Ma) almost coincides with the previously estimated age of quartz syenites from the South Ol’khon pluton (495 ± 6 Ma). The plutons occupy the same position in the regional structure. The granitoids underwent final deformations and metamorphism at 464 ± 11 Ma. The Tutai pluton consists of moderately potassic granites, whereas the South Ol’khon pluton is made up of quartz syenites and granites. The geochemical characteristics of the granites from both plutons (low Y and Yb contents, fractionated REE patterns) indicate their formation under conditions of garnet crystallization in deep crustal restite. The higher Y and Yb contents of the South Ol’khon quartz syenites as compared with those of the granites suggest the lack of equilibrium between the quartz syenite magmas and garnet parageneses during their formation or evolution. The Tutai and South Ol’khon granites were derived from quartz-feldspar crustal rocks, whereas the South Ol’khon quartz syenites might have originated from a mixed (crust-mantle) source. It is presumed that the granitoids formed within accretion-thickened crust. Early accretion, which has been first identified in the region, affected not only the Pribrezhnaya zone (the zone of the Tutai and South Ol’khon plutons) but also the entire Anga–Satyurty megazone of the Ol’khon terrane. The accretion ended with the convergence and oblique collision of the Ol’khon terrane and Siberian continent, when strike-slip tectonics became ubiquitous. 相似文献
20.
The uranium (U) content and 234U/238U activity ratio were determined for water samples collected from Korea's Han River in spring, summer, and winter 2006 to provide data that might constrain the origin of U isotope fractionation in river water and the link between U isotope systematics in river waters and the lithological nature of the corresponding bedrock. The large difference in the major dissolved loads between the two major branches of the Han River, the North Han River (NHR) and South Han River (SHR), is reflected in the contrasting U content and 234U/238U activity ratio between the tributaries: low U content (0.08–0.75 nM; average, 0.34 nM) and small 234U/238U activity ratio (1.03–1.22; average, 1.09) in the NHR; and high U content (0.65–1.98 nM; average, 1.44 nM) and large 234U/238U activity ratio (1.05–1.45; average, 1.24) in the SHR. The large spatial differences in U content and 234U/238U activity ratio are closely related to both lithological differences between the two tributaries and groundwater input. The low U content and small 234U/238U activity ratio in the NHR arise mainly from a combination of surface and meteoric weathering of the dominant silicate rocks in this branch and congruent dissolution of already weathered (secular equilibrium) materials. In contrast, the high U content and large 234U/238U activity ratio in the SHR are ascribed to the dissolution of carbonates and black shales along with significant inputs of deep groundwater. 相似文献